| 학회 | 한국공업화학회 |
| 학술대회 | 2017년 봄 (05/10 ~ 05/12, 광주 김대중컨벤센센터(Kimdaejung Convention Center)) |
| 권호 | 21권 1호 |
| 발표분야 | 정밀화학 |
| 제목 | Nitrodeiodination of bistriiodoazole derivatives |
| 초록 | High-energy density materials(HEDMs) which have high ratio of nitrogen shows a high detonation performance and thermal stability which is the goal of designing advanced energetic materials. Azole derivatives which adopted nitro group or azide group have high nitrogen contents. They are considered as good candidates for high explosives. We synthesized 3,4,5-triiodo-pyrazole(TIP) 2,4,5-triiodo-1H-imidazole(TII) from commercially available 1H-pyrazole and 1H-imidazole as a precursor to synthesize azole-based high explosives. Herein, we will introduce 4 different bistriiodoazole derivatives by coupling reaction of TIP and TII and nitrodeiodination study of these compounds. |
| 저자 | 조재영, 이병일, 신혜정, 김남태, 박종범, 김영규 |
| 소속 | 서울대 |
| 키워드 | azole; high explosives; nitrodeiodination |
