화학공학소재연구정보센터
학회 한국고분자학회
학술대회 2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터)
권호 37권 1호
발표분야 고분자가공/복합재료
제목 Synthesis of Mono-dispersed Silica@PMMA Microparticles
초록 A demand of mono-dispersed silica particles with various sizes is steadily increasing due to their wide range of applications. In order to prepare silica particles, we used two phase method, which employs L-arginine amino acid as a hydrolysis catalyst. The size range of silica particles through this method could be controlled from 20 nm to 80 nm, and these mono-disperse silica particles could be successfully used as seeds in the conventional Stöber method. Furthermore, the 100nm particles were treated with 3-trimethoxysilyl propyl methacrylate (MPS) to polymerize methyl methacrylate (MMA) on the surface of the silica particles. Shell thickness of silica@PMMA particles could be increased by increasing the amount of MMA monomer. We expect that the core-shell particles have discriminative properties such as optical, biological and electric properties compared with simple colloids’ ones.
저자 이준석, 임채호, 양승만
소속 KAIST 생명화학공학과
키워드 Core-shell particle; Silica; PMMA
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