| 학회 |
한국공업화학회 |
| 학술대회 |
2015년 봄 (04/29 ~ 05/01, BEXCO (부산)) |
| 권호 |
19권 1호 |
| 발표분야 |
고분자_포스터 |
| 제목 |
Transition Metal-Catalyzed Polymerization of 1-Hexyne: Synthesis and Properties of Poly(1-hexyne) |
| 초록 |
The polymerization of 1-hexyne was carried out by various transition metal catalysts. The instrumental analysis data on the polymer structure revealed that the present polymer have the conjugated polyene backbone system with n-butyl substituents. This polymer showed UV-visible absorption band at 276 nm and PL spectrum at 415 nm, indicating relatively blue-shifted PL maximum value. The cyclic voltammograms indicated that the kinetics of the redox process are close to the diffusion-control process. The band gap energy of polymer was estimated to be 2.98 eV and HOMO and LUMO level values of polymer were 5.35 and 2.37 eV, respectively. |
| 저자 |
정미나1, 박영일2, 제갈영순3, 진성호4, 임권택5, 박종욱1
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| 소속 |
1가톨릭대, 2한국화학(연), 3경일대, 4부산대, 5부경대 |
| 키워드 |
Polacetylene; aliphatic; 1-hexyne; characterization; cyclovoltamogram
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| E-Mail |
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