학회 |
한국공업화학회 |
학술대회 |
2018년 봄 (05/02 ~ 05/04, 대구 엑스코(EXCO)) |
권호 |
22권 1호 |
발표분야 |
환경에너지_포스터 |
제목 |
Photocatalytic carbon dioxide Conversion to Hydrocarbon Fuel with carbon and nitrogen doped Sodium Titanate Nanotubes |
초록 |
Carbon and nitrogen co-doped sodium titanate nanotubes active under simulated solar light are synthesized by a simple two-step process comprising an alkaline hydrothermal technique followed by calcination. Different samples of C,N-TNT with varied dopant concentrations are achieved by changing the amount of urea as a nitrogen and carbon dopants. The C,N-TNT sample with an intermediate doping concentration yields the maximum methane yield of 9.75 μmol/g h. The key factors contributing in the improvement of photocatalyst performance includes light absorption, surface area and Na+ ions concentration in TNT acting asCO2adsorption site and photogenerated electrons recombination centers. The higher doping levels results in lower specific surface areas leading to decrease in photocatalyst performance. Our results suggest co-doping of nanostructured photocatalysts is an excellent pathway for improving textural and photocatalytic properties for the respective application domain. |
저자 |
황윤주, 인수일
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소속 |
대구경북과학기술원 |
키워드 |
co2 conversion; doped c&n
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E-Mail |
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