| 학회 | 한국공업화학회 |
| 학술대회 | 2008년 봄 (05/09 ~ 05/10, 한양대학교(안산)) |
| 권호 | 12권 1호 |
| 발표분야 | 고분자 |
| 제목 | Mn(III)-mediated oxidation and polymerization of phenolic compounds |
| 초록 | Manganese peroxidase (MnP) has been found to play a role in the degradation of lignin and catalyze the oxidation of Mn(II) to Mn(III). Mn(III) is a diffusible oxidant, able to oxidize a variety of phenolic substrates via the formation of the phenoxy radicals at a distance away from the active site of MnP. Alternatively, the condensation of radicals in mixtures of solvents and water would lead to polymerization products. In order to better understand the oxidation and polymerization of phenolic compounds by manganese peroxidase, Mn(III)-mediated oxidation and polymerization of phenolic model compounds were investigated. |
| 저자 | 이동익1, 황상필2, 최지연1, 김찬진1, 안익성1 |
| 소속 | 1연세대, 2삼성엔지니어링 기술(연) |
| 키워드 | Mn(III); MnP; oxidation; polymerization; phenolic compounds |
