학회 |
한국화학공학회 |
학술대회 |
2008년 가을 (10/23 ~ 10/24, 부산 BEXCO) |
권호 |
14권 2호, p.3532 |
발표분야 |
촉매 및 반응공학 |
제목 |
The Role of Calcium added to Ni-based Hydrotalcite Catalyst for LPG Steam Reforming |
초록 |
Steam reforming of LPG over Ni/MgCaAl catalysts were carried out in a temperature range of 700℃, at atmospheric pressure with space velocity of 20,000 h-1 and feed molar ratio of H2O/C = 1.0. The catalysts were prepared by a co-precipitation. The Ni/MgCaAl catalyst showed higher resistance for the sintering of active metal than Ni-based hydrotalcite catalyst prepared by conventional method. It was found that Ni/MgCaAl catalyst showed high inhibition to the formation of carbon compared to Ni-based catalysts and maintained the activity at 700℃ for 50 h. The results suggest that the Ni/MgCaAl catalyst can be applied for the steam reforming of LPG. |
저자 |
김대현1, 이병권1, 최재석2, 김명준2, 홍석인3, 문동주1
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소속 |
1한국과학기술(연), 2SK에너지, 3고려대 |
키워드 |
hydrotalcite; LPG; steam reforming; Ni-based catalyst
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E-Mail |
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원문파일 |
초록 보기 |