화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2001년 가을 (10/19 ~ 10/20, 한밭대학교)
권호 7권 2호, p.2481
발표분야 촉매/반응공학
제목 MCM-41상에 고정화된 키랄 살렌의 광학선택적 촉매 활성
초록 The chiral salen complexes immobilized on mesoporous material were applied as catalysts in the epoxidation of olefins, and the reduction of aromatic ketone, addition of trimethylsilylcyanide to benzaldehyde. According to our studies, unsymmetrical chiral salens immobilized on MCM-41 represented relatively high ee% for this reaction. The enantioseletive hydrolytic resolution of racemic epoxides was performed in the ZSM-5/MCM-41 membrane system containing chiral salen complexes.
저자 김건중, 김주호, 최성대
소속 인하대
키워드 Chiral; Enantioselectivity; MCM-41
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