| 학회 |
한국고분자학회 |
| 학술대회 |
2007년 봄 (04/12 ~ 04/13, 제주 ICC) |
| 권호 |
32권 1호 |
| 발표분야 |
고분자 가공/복합재료 |
| 제목 |
Fabrication of densely packed titania nanosheet multi-layer thin film and polymeric nanocomposites |
| 초록 |
Titania nanosheets of unilamella two-dimensional crystallites were synthesized by the flux method and exfoliation process to give titania nanosheets (K0.8Li0.267Ti1.733O4). A multilayer film of titania nanosheet crystallites was fabricated using poly (diallyldimethylammonium chloride) in the layer-by-layer (LBL) process, where gold strongly interacted with the amine group to give a robust nanostructure via ultrasonication treatment and UV-light irradiation. Titania nanosheets were tiled without gap as a consequence overlapped and crumpled nanosheets by ultrasonication treatment. Photoinduced hydrophilic conversion of titanate surfaces were obtained by UV irradiation and transformed into the titania multi-layer thin film of polymer free form. The titania multi-layer film and its polymeric nanocomposites were analyzed using FT-IR spectroscopy, X-ray diffraction, atomic force microscopy, high-resolution transmission electron microscopy, spectroscopic ellipsometry and UV-vis spectroscopy. |
| 저자 |
이광협희1, 남재도2, 김동욱3, 백지원3, 류무선3, 김운천4, 임성택4, 정율교4
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| 소속 |
1성균나노과학기술원, 2성균나노과학기술원 / 성균관대, 3성균관대, 4삼성전기중앙(연) |
| 키워드 |
nanosheet; multilayer; layer-by-layer
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| E-Mail |
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