화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2008년 가을 (11/12 ~ 11/14, ICC 제주)
권호 12권 2호
발표분야 환경에너지
제목 Surface Modification of Activated Carbon Nanotubes For increasing CO2 Adsorption
초록 In this work, nitrogen enriched activated carbon nanotubes (A-CNTs) were used to measure the characterization of CO2 adsorption. A-CNTs were prepared by impregnation with amine in methanol after chemical activation methods using KOH. Nitrogen enriched A-CNTs were characterized by mass titration method, X-ray photoelectron spectroscopy (XPS), and BET measurements. CO2 capture capacity as a function of temperature was measured by thermogravimetric analysis (TGA). From the result, the impregnated amine group on A-CNTs led to an increase the basicity and nitrogen content of the carbon. As temperature, consistently CO2 capture ability of amine group impregnated A-CNTs decreased as compared with neat A-CNTs. It was due to the stronger interactions between the gaseous CO2 and the amine groups presented on the carbon surfaces studied.
저자 장동일, 박수진
소속 인하대
키워드 Keywords : activated carbon nanotubes (A-CNTs); CO2 adsorption; chemical activation
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