| 학회 |
한국고분자학회 |
| 학술대회 |
2003년 봄 (04/11 ~ 04/12, 연세대학교) |
| 권호 |
28권 1호, p.238 |
| 발표분야 |
복합재료 |
| 제목 |
Preparation of monodisperse silsesquioxane spheres |
| 초록 |
Amine groups in 3-aminoalkoxysilanes were examined as catalysts in sol-gel reactions of different precursors, tetralkoxysilanes and organotrialkoxysilanes. It was striking that 3-aminopropyltrimethoxysilane (APTMOS) caused formation of monodisperse spheres regardless of water compatibility of precursors. Optical microscopic observation, Si(29) NMR spectroscopy and IR spectroscopy analysis and elemental analysis showed that APTMOS was playing multiple roles. Some of spheres were subjected to chemical reactions to demonstrate the availability of functional group for different chemical reactions. New precursors were prepared from APTMOS and spheres were also prepared to demonstrate the effect of of amine on self-condensation. |
| 저자 |
임미선;임진숙;임미선 |
| 소속 |
배재대 |
| 키워드 |
silsesquioxane; silica-organic hybrid
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| E-Mail |
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