| 학회 |
한국화학공학회 |
| 학술대회 |
2008년 가을 (10/23 ~ 10/24, 부산 BEXCO) |
| 권호 |
14권 2호, p.3533 |
| 발표분야 |
촉매 및 반응공학 |
| 제목 |
Immobilization of Ionic Liquid on Amorphous Silica for the Synthesis of Cyclic Carbonate from Carbon Dioxide and Allyl Glycidyl Ether |
| 초록 |
In this work, imidazolium salt ionic liquid on amorphous silica catalysts were prepared and their catalytic performance were investigated in the chemical fixation of CO2. A variety of catalysts were synthesized by manipulating both the HCl to water ratios and TEOS to imidazolium solution ratios. The prepared catalysts were characterized using a number of physico-chemical measurements including EA, BET and 29Si MAS-NMR, showed that the ionic liquid formed an adduct with the chloropropyl groups attached to the silica surface. The synthesis of cyclic carbonate via cycloaddition of CO2 to epoxide is one of effective routes of CO2 chemical fixation. The catalytic activity studies were performed for the addition of CO2 to allyl glycidyl ether (AGE) to produce a cyclic carbonate. The effect of carbon dioxide pressure on the conversion and selectivity were discussed. The imidazolium salt ionic liquid on amorphous silica catalysts showed very good catalytic activity for the synthesis of cyclic carbonate. |
| 저자 |
심혜림, 이미경, 유정인, 우다야 쿠마르, 김경훈, 박대원
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| 소속 |
부산대 |
| 키워드 |
Amorphous silica; Imidazolium salt ionic liquid; Carbon dioxide; Cyclic carbonate
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| E-Mail |
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| 원문파일 |
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