| 학회 |
한국공업화학회 |
| 학술대회 |
2005년 가을 (10/28 ~ 10/29, 건국대학교) |
| 권호 |
9권 2호 |
| 발표분야 |
정밀화학 |
| 제목 |
Synthesis of Bis(silyl)methanes. Coupling Reaction of Polychloromethanes with Trichlorosilane |
| 초록 |
The Si–C coupling reaction of polychloromethanes (RCH3-nCln: R= Cl, Me, Ph, n=2~3) with trichlorosilane in the presence of n-Bu4PCl as catalyst give the bis-silylation compounds as major products. The reactions of CCl4 and CH2Cl2 occur at the temperatures of 32 oC and 150 oC to give Si-C coupling products, respectively. At the High temperature of 170 oC, Tis-silylation products, bis(trichlorosilyl)methanes and (dichlorosilyl)(trichlorosilyl)methane, are obtained as major products. |
| 저자 |
정동의1, 황영애2, 한준수1, 임원철1, 강승현1, 유복렬1
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| 소속 |
1한국과학기술(연), 2상명대 |
| 키워드 |
Bis(silyl)methanes; Si–C coupling; trichlorosilane
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| E-Mail |
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