| 학회 |
한국고분자학회 |
| 학술대회 |
2018년 가을 (10/10 ~ 10/12, 경주컨벤션센터) |
| 권호 |
43권 2호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Fabrication of Various Sensor Systems Using Polydiacetylenes |
| 초록 |
Polydiacetylenes (PDAs) have a special character in which their color changes from blue to red by outer stimuli. 1) A glucose sensor was fabricated using a PDA. H2O2 formed by the reaction between glucose and glucose oxidase functioned as the initiator. The glucose concentration could be detected that turns the solution to blue. 2) PDA and poly(sodium 4-styrene-sulfonate) (PSS) were alternately stacked to form a layer-by-layer (LBL) film. The formed-film sensor showed higher sensitivity than the vesicle solution. 3) The noble vesicular system of PDA showed a red shift by the permeation through the vesicular layers from within the vesicle. 4) The thermal chromatic sensitivity of PDAs with 10,12-pentacosadiynoic acid (PCDA) derivatives which have a hydroxyl group (HEEPCDA) were investigated. The vesicle solution with polymerized HEEPCDA exhibited a reversible chromatic response during the heating and cooling cycle in D2O, but not in H2O. |
| 저자 |
신민재1, 김민희2, 신재섭2
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| 소속 |
1세명대, 2충북대 |
| 키워드 |
polydiacetylene; sensor; color transition;
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| E-Mail |
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