| 학회 |
한국고분자학회 |
| 학술대회 |
2012년 봄 (04/12 ~ 04/13, 대전컨벤션센터) |
| 권호 |
37권 1호 |
| 발표분야 |
기능성 고분자 |
| 제목 |
Crosslinkable Organic-Inorganic Hybrid Materials of poly(4,7-bis(5- triethoxy silylvinyl-3-hexylthiophen-2-yl)-benzothiadiazole for LED applications |
| 초록 |
Novel organic-inorganic hybrid materials of poly(4,7-bis(5-triethoxysilyl vinyl-3-hexyl thiophen-2-yl)-benzothiadiazole)(PTBT-Si) were synthesized for LED applications. 4,7-Bis(3-dodecylthiophen-2-yl)-benzothiadiazole was synthesized by Suzuki coupling of 4,7-dibromo-2,1,3-benzothiadiazole and 2-(3-hexylthiophen-2-yl)-4,4,5,5-tetramethyl-[1,3,2]- dioxaborolane using a tetrakis(triphenylphosphine)Palladium(0). NBS reaction was performed on 4,7-bis(3-hexylthiophen-2-yl)-benzothiadiazole to obtain its dibromo compound. Poly(4,7-bis(5-bromo-3-hexylthiophen-2-yl)-benzothiadiazole) (PTBT) was prepared via Yamamoto-type coupling reaction using a Ni(COD)2 which was further modified into the silane-containing oligomeric compound (PTBT-Si) by Heck coupling with vinyltriethoxysilane using Pd[P(tBu)3]2 for the preparation of crosslinked thin films for LED applications. The molecular structures and film morphology were identified by various characterization tools. |
| 저자 |
한진영1, 노승주1, 석민균1, 허성익1, 장세현1, 안행희1, 김성현2, 권용구1
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| 소속 |
1인하대, 2경희대 |
| 키워드 |
Polymer synthesis; TBT; LED
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| E-Mail |
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