화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2010년 봄 (04/22 ~ 04/23, 대구 EXCO)
권호 16권 1호, p.617
발표분야 열역학
제목 Correlation of Phase Equilibrium Data of CO2 + Water Mixtures Containing Gas Hydrate using NLF-HB and MF NLF-HB EoS
초록 The reliable phase equilibrium data and prediction of CO2 + Water mixture are required for the CO2 sequestration process. Some of experimental data are available for water rich phase containing gas hydrate, which alsoagree well with the correlation data using NLF-HB EoS(Hydrogen Bonding Non-random Lattice Fluid EoS). But for CO2 rich phase, experimental data are rare and also the correlation results with one binary energy parameter fitted from water rich phase data could not explain the experimental data. Two binary energy parameters based on multi-fluid approximation had been introduced in this study. The phase equilibrium data of LW-LCO2, LW-H-LCO2, LW-H-V, and LCO2-H were correlated with NLF-HB Eos and MF NLF-HB Eos. The correlation results of experimental data of CO2 rich phasewith two binary energy parameters were betterand water rich phase data were correlated well with both models.
저자 서명도1, 이주호2, 김선형1, 이철수1, 강정원1
소속 1고려대, 2서강대
키워드 phase equilibrium; gas hydrate; NLF; Multi Fluid; CO2
E-Mail
VOD VOD 보기
원문파일 초록 보기