화학공학소재연구정보센터
학회 한국공업화학회
학술대회 2017년 봄 (05/10 ~ 05/12, 광주 김대중컨벤센센터(Kimdaejung Convention Center))
권호 21권 1호
발표분야 환경에너지
제목 Preparation of Chelated Iron Complexes and H2S Removal Activity
초록 Liquid desulfurization catalyst of iron chelated complexes were prepared using alpha-hydroxy acids(AHAs, citrate acid and tartarate) and ethylene diamine tetraacetate (EDTA) as chelating materials, respectively. The typical catalyst solution contained [Fe]=10,000 ppm with the 10% excess equivalent ratio of chelate materials and the pH=8.0 using phosphate buffer solution. The desulfurization performance of Fe (III)/Fe (II) chelating agents was investigated on a simulated sulfur-containing industrial gas composed of H2S and N2 in a liquid-gas reactor. In desulfurization process, the diluted  liquid catalyst solutions were sprayed from the top against up-stream H2S gas. The H2S gas removal activity according to the kind of catalyst solution, catalyst concentration, reaction period, and reproducibility was systematically compared.
저자 김유득1, 박정철1, 우경두1, 이지호2, 한양수2
소속 1(주)해림엔지니어링, 2(주)나노스페이스
키워드 catalyst; Desulfurization; Chelating agent
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