화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2007년 가을 (10/26 ~ 10/27, 한국과학기술원)
권호 13권 2호, p.1636
발표분야 분리기술
제목 용매 추출에 의한 Tetrahydrofuran의 회수
초록 The efficient separation of ring-containing compounds (e. g., cyclic ethers and cyclic alcohols) from aqueous solutions is important in the chemical industry, where many solvents have been tested to improve such recovery.
Tetrahydrofuran (THF) is an organic solvent, an important organic raw material, and the precursor of polymers. Due to its proton-accepting nature, it is used as a solvent in many chemical industries. Many chemical and pharmaceutical industries encounter problem in separating THF from aqueous waste streams since their mixture form azeotropes at low compositions of water.
The purpose of this work is to determine liquid-liquid equilibrium (LLE) data of water + THF + solvent (n-heptane, butyl acetate, isopropyl acetate, isoamyl alcohol) at 25 ℃ and atmospheric pressure. The selection of the optimum solvent to separation THF from aqueous solution was investigated. In addition, the LLE data have been predicted with the UNIFAC method, and they are compared with the experimental data at 25 ℃.
저자 김영규, 옥동석, 박동원
소속 동아대
키워드 Solvent extraction; Liquid-liquid equilibrium; Ternary system; UNIFAC
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