화학공학소재연구정보센터
학회 한국재료학회
학술대회 2016년 봄 (05/18 ~ 05/20, 여수 디오션리조트 )
권호 22권 1호
발표분야 F. 광기능/디스플레이 재료 분과
제목 A long-term stable electrochromism of P3HT by surfactant-assisted graphene oxide layer
초록   The electrochemical stability of organic materials has been known as unstable characteristics during the redox reactions, which is mainly due to degradation caused by the mechanical problems in electrolytes during the ionic exchanges. As one of the effective methods for the stable performance of EC reactions against such problems, incorporation of graphene oxide (GO) into the polymer matrix has been introduced to solve the stability issue because GO has known to significantly improve the physical properties of polymers via strong GO-polymer interactions. Moreover, as one of the advanced techniques, modified GO surface through the incorporation of surfactant was broadly reported that its hybrid GO can promotes its hydrophobic properties for the better mutual interactions with specific polymer chains. In this study, we investigated the enhanced electrochromic properties of polymer electrochromic materials (P3HT) induced GO-octadecylamine (ODA) complex protective layer. In order to form an ultra-thin GO-ODA layer on P3HT films, GO-ODA composite was transferred to on the spin-coated P3HT layer by using Langmuir-Schaefer techniques. By ths technique, highly covered GO-ODA protective layer on the P3HT layer was obtained having strong interactions with them. These features induced a superior long-term stability compared to pristine P3HT layer against electrochromic reactions.
저자 김태호1, 최기인2, 김혜리2, 오성현1, 구자승2, 나윤채1
소속 1한국기술교육대, 2한국원자력(연)
키워드 <P>Langmuir-Schaefer; Graphene oxide; P3HT; Surfactant;  Protective layer;  Electrochromism; Stability</P>
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