| 학회 |
한국고분자학회 |
| 학술대회 |
2021년 가을 (10/20 ~ 10/22, 경주컨벤션센터) |
| 권호 |
46권 2호 |
| 발표분야 |
대학원생 구두발표(토론I): 분자전자용 공액고분자 소재 및 소자의 미래 |
| 제목 |
Molecular-Orientation-Driven Transient Behavior of Semicrystalline Polymeric Mixed Conductors |
| 초록 |
Despite the importance of transient behavior in organic mixed ionicelectronic conductors, there are very few studies on material characteristics affecting ion drift and transient responses of corresponding organic electrochemical transistors (OECTs). In this work, we investigated the effect of molecular orientation of a polymeric mixed conductor system with glycol side chains on the transient behavior of OECTs by varying the co-monomer unit (2,2’-bithiophene or phenylene) used in conjunction with a novel 1,4-dithienylphenylene monomer. Two polymers with similar mixed conductivity and electrochemical characteristics except molecular orientation were successfully synthesized. The comprehensive analysis of the OECT characteristics showed that the molecular orientation affects the length of the ion-drift pathway correlated with ion mobility, resulting in different transient behavior in OECT devices. |
| 저자 |
김지환1, Roman Halaksa2, 김건우1, 조일영1, peter anthony finn2, 이인호3, 이종원1, 김영석1, 안형주4, 박성준3, Christian Bech Nielsen2, 윤명한1
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| 소속 |
1광주과학기술원, 2Queen Mary Univ. of London, 3아주대, 4포항가속기(연) |
| 키워드 |
organic mixed conductors; molecular orientation; organic electrochemical transistors; transient behavior
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| E-Mail |
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