화학공학소재연구정보센터
학회 한국재료학회
학술대회 2011년 봄 (05/26 ~ 05/27, 제주 휘닉스 아일랜드)
권호 17권 1호
발표분야 A. Information and Sensor Materials(정보소재 및 센서)
제목 B-site substitution effects on the piezoelectric properties of Bi-based lead-free ceramics
초록 B-site substitution with isovalent and donor impurities was compared in terms of the piezoelectric properties of Bi-based ABO3 perovskite ceramics. X-ray diffraction study revealed that both impurities bring about degradation in their ferroelectric properties as well as piezoelectric characteristics. However, there existed a difference between the isovalent and heterovalent impurities that influence a phase transformation of ferroelectric anisotropic-to-electrostrictive pseudocubic symmetry. Based upon analyses including the crystal, microstructure, dielectric, ferroelectric properties, we believed that A-site vacancies in the ABO3 ceramic significantly contribute to a ferroelectric-nonpolar phase transition, which give rise to lead to a giant strains. The present paper will discuss the origin of   giant strains in Bi-based perovskite ceramics.
저자 한형수, 강진규, 윤창호, 이한복, 김경종, 이재신
소속 울산대
키워드 압전; 강유전체; 세라믹스; 도핑
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