| 학회 |
한국고분자학회 |
| 학술대회 |
2018년 가을 (10/10 ~ 10/12, 경주컨벤션센터) |
| 권호 |
43권 2호 |
| 발표분야 |
고분자합성 |
| 제목 |
Synthesis of high molecular weight furan based copolyester and its thermal, mechanical properties |
| 초록 |
Furan-2,5-dicarboxylic acid (FDCA) is considerable attention as substituent that can replace terephthalic acid as a biomass derived monomer. By the two step polymerization, we have synthesized a high molecular weight furan based copolyester, poly(butylene adipate-co-furanoate) (PBAF). Depending on the feed ratio of acid monomers, adipic acid and dimethyl furan-2,5-dicarboxylate, block composition could be controlled. Amongst PBAF series, PBAF90 showed highest tensile strength (σ) of 83.4 MPa and elongation at break (ε) of 501 %. Synthesized FDCA based polyester surpasses the mechanical properties of conventional PBAT. These results were induced by the effective micro-separation between hard and soft domains owing to the rigidity of the furan ring and flexibility of butylene adipate block that leads to elastomeric behavior. |
| 저자 |
김태호1, 구준모1, 신명숙1, 김주현2, 박제영1, 오동엽1, 황성연1
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| 소속 |
1한국화학(연), 2부경대 |
| 키워드 |
furan-2; 5-dicarboxylic acid; bio-based; copolymer; PBAF; tensile strengh
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| E-Mail |
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