화학공학소재연구정보센터
학회 한국화학공학회
학술대회 2011년 가을 (10/26 ~ 10/28, 송도컨벤시아)
권호 17권 2호, p.1618
발표분야 에너지
제목 Autothermal Reforming of Methane to Hydrogen in a Stand-alone Reformer
초록 Autothermal reforming includes the exothermic partial oxidation and the endothermic steam reforming under thermally neutral conditions. In this work, stand-alone autothermal reformer that is developed as 1kWe scale consists of two distinct zones; a start-up zone and an autothermal reforming zone. In the start-up zone, electrically heated converter(EHC) with partial oxidation catalyst-coated metal monolith helps in heating upthe temperature above 700℃ within two minutes. Accordingly, the autothermal reforming zone has a temperature between 550℃ and 650℃.
Autothermal reforming of methane is carried out at S/C ratio 1~2, O/C ratio 0.4~0.6, and GHSV 10,000~20,000hr-1. Under this condition, methane conversion of 91.6%, hydrogen yield of 74.2% on dry basis can be achieved and 1 mol of methane can produce 2.7 mol hydrogen at equilibrium reformer temperature of around 600℃.
저자 구정분, 권현지, 김영애, 곽인섭, 신장식
소속 RTI엔지니어링
키워드 autothermal reforming; methane; stand-alone reformer; lectrically heated converter(EHC); metal monolithic support
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