Journal of Adhesion Science and Technology, Vol.10, No.4, 327-339, 1996
Toughening of impenetrable interfaces by polydisperse tethered polymer chains: Effect of tethered chain length
Experiments were conducted to evaluate the effect of polydisperse tethered chains on the toughness of an impenetrable interface. The results indicate that tethered chains improved the toughness of such interfaces - an improvement that we attribute to an interaction between the tethered chains and the matrix free chains. An increase in the tethered chain length relative to the free chain length, plus the natural polydispersity of the tethered chains, appears to underlie this beneficial interaction.
Keywords:PS-PMMA COPOLYMER;PULL-OUT TEST;DIBLOCK COPOLYMER;BLOCKCOPOLYMERS;MOLECULAR-WEIGHT;IMMISCIBLE POLYMERS;POLYSTYRENE;BLENDS;MECHANISMS;SURFACE