The aim of the present investigation is to examine differences between O-2/N-2 and O-2/CO2 atmospheres during devolatilization and char conversion of a bituminous coal at conditions covering temperatures between 1173 K and 1673 K and inlet oxygen concentrations between 5 and 28 vol.%. The experiments have been carried out in an electrically heated entrained flow reactor that is designed to simulate the conditions in a suspension fired boiler. Coal devolatilized in N-2 and CO2 atmospheres provided similar results regarding char morphology, char N-2-BET surface area and volatile yield. This strongly indicates that a shift from air to oxy-fuel combustion does not influence the devolatilization process significantly. Char combustion experiments yielded similar char conversion profiles when N-2 was replaced with CO2 under conditions where combustion was primarily controlled by chemical kinetics. When char was burned at 1573 K and 1673 K a faster conversion was found in N-2 suggesting that the lower molecular diffusion coefficient of O-2 in CO2 lowers the char conversion rate when external mass transfer influences combustion. The reaction of char with CO2 was not observed to have an influence on char conversion rates at the applied experimental conditions. (C) 2010 Elsevier Ltd. All rights reserved.