An optimized reduced mechanism of n-heptane including 42 species and 58 elementary reactions adapted to charge stratification combustion is developed first in this study. Some engine experiments and a fully coupled CFD and reduced chemical kinetics model with n-heptane as fuel are adopted to investigate the combustion processes of HCCI-Iike charge stratification combustion aimed at diesel HCCI application. For premixed/direct-injected stratification combustion, the low temperature reaction occurs in the regions with homogeneous fuel first and high temperature reaction begins from high fuel concentration regions involved in the spray process. With the increase of the injection ratio, the high temperature reaction occurs in advance, the pressure rise rate reduces, UHC emissions decrease and CO emissions increase. At larger injection ratio, the onset of the high temperature reaction advances and the maximum pressure rise rate decreases with the retarding of injection timing. UHC and CO emissions have relation to the fuel spray penetration at different injection timings. NO(x) emissions increase rapidly with the increase of the stratification degree. Crown Copyright (C) 2008 Published by Elsevier Ltd. All rights reserved.