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Current Applied Physics, Vol.12, No.5, 1381-1385, 2012
Effect of oxygen partial pressure and annealing on nanocrystalline p-type ZnO:Sb thin films
We have investigated the effect of oxygen partial pressure and annealing on nanocrystalline p-type Sb-doped ZnO thin films, grown by pulsed laser deposition, with hole concentration of 6.5 x 10(18)/cm(3) and mobility of 53 cm(2)/V-s. Uses of higher working pressure or annealing are found to reduce carrier concentration. A strong correlation is observed between carrier concentration and the violet (3.02 eV) emission related to free Zn-vacancy; stronger the violet emission, smaller the carrier concentration. In contrast to earlier suggestion of using higher oxygen pressure for obtaining p-type conductivity, the present results show a deterioration of the quality of film. (C) 2012 Elsevier B. V. All rights reserved.