Bioresource Technology, Vol.102, No.2, 1308-1315, 2011
Exploitation of hemicellulose, cellulose and lignin from Hesperaloe funifera
This work seeks the integral use of all major components of Hesperaloe luny-era, separating hemicelluose by hydrothermal treatments; cellulose by pulping processes; and exploitation of lignin of pulping liquor by pyrolysis and gasification processes. By using sulfuric acid in the hydrothermal treatment (150-190 degrees C, 0-20 min after reaching operating temperature, 6-10 liquid/solid ratio, 0.1-0.5% sulfuric acid), the glucose and xylose of liquid fraction increase from 1.5% to 5.9%, and 4.0% to 12.4%, respectively; the yields of solid fraction decrease from 91.6% to 79.5%, and the lignin content increase from 23% to 32%. Pulps and paper sheets obtained from solid fractions hydrothermal treatments and from raw material pulped with diethanolamine, are worse than those obtained with soda-anthraquinone (Yield 57.8%; kappa number 24.9; Viscosity 711 mL/g; Brightness 54.8%; Tensile index 73.6 Nm/g; Stretch 2.84%; Burst index 6.13 kN/g and Tear index 1.69 mNm(2)/g). By acidification (pH 6) of soda pulping liquor it separate lignin-rich solids, which by pyrolysis gave a gas containing 1.13% H(2), 31.79% CO and 1.86% CH(4) by weight. Gasification of the same sample provided a gas containing 0.18% H(2), 24.50% CO and 17.75% CH(4). (C) 2010 Elsevier Ltd. All rights reserved.