화학공학소재연구정보센터
Journal of Crystal Growth, Vol.355, No.1, 129-139, 2012
Thermal-capillary analysis of the horizontal ribbon growth of silicon crystals
A thermal-capillary, finite-element model is developed for the Horizontal Ribbon Growth (HRG) system to study the characteristics of the process and to assess its feasibility to grow silicon sheets. The mathematical model formulation rigorously accounts for mass, energy, and momentum conservation while simultaneously representing capillary physics of the menisci, tracking of the solidification front, and self-consistent determination of ribbon thickness. Model results show the potential, with suitable heat transfer design, for the HRG process to achieve the formation of an extended, wedge-shaped interface with latent heat dissipation primarily in a direction perpendicular to the pulling direction. These attributes allow the HRG system to achieve higher pull rates under lower thermal gradients than vertical ribbon growth systems. Crystal thickness is predicted to decrease with increasing pull rate; however, contrary to prior analyses, pull rate limits are identified as limit-point bifurcations to quasi-steady solutions. Multiple solution branches correspond to stable and unstable operating states, exhibiting dramatically different interfacial shapes that identify possible failure mechanisms. (C) 2012 Elsevier B.V. All rights reserved.