Inorganic Chemistry, Vol.51, No.9, 4906-4908, 2012
[W(bipy)(CN)(6)](-): A Suitable Metalloligand in the Design of Heterotrimetallic Complexes. The First Cu(II)Ln(III)W(V) Trinuclear Complexes
The first 3d-4f-5d heterotrimetallic complexes using [W-V(bipy)(CN)(6)](-) as a metalloligand were synthesized (bipy = 2,2'-bipyridine). The structural and magnetic properties of three [Cu(II)Ln(III)W(V)] complexes (Ln = Gd, Ho, Tb) are discussed.