화학공학소재연구정보센터
Langmuir, Vol.27, No.23, 14014-14024, 2011
Directed Assembly of BaFe12O19 Particles and the Formation of Magnetically Oriented Films
We have studied the preparation of oriented BaFe12O19 films produced using electrophoretic deposition (EPD). Highly anisotropic, platelike BaFe12O19 particles were synthesized under hydrothermal conditions, and from these particles, stable suspensions were prepared in 1-butanol by the addition of dodecylbenzene sulfonic acid as a surfactant. The interplay of the interaction forces between the suspended particles and the forces acting on the particles during the EPD directed the particles' assembly in the plane of the substrate. The most significant effect on the orientation of the films was the diameter-to-thickness ratio of the particles, which was experimentally confirmed with X-ray analyses, electron microscopy, and magnetic measurements. The abnormal grain growth that accompanied the sintering at 1150 degrees C further improved the overall orientation of the films, which showed highly anisotropic magnetic behavior with a remanent-to-saturation magnetization ratio exceeding 0.8.