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Journal of the Electrochemical Society, Vol.158, No.10, P118-P121, 2011
Temperature Dependent Emission of Strontium-Barium Orthosilicate (Sr2-xBax)SiO4:Eu2+ Phosphors for High-Power White Light-Emitting Diodes
Samples of (Sr1.9-xBax)SiO4:Eu-0.1 were synthesized by a solid-state reaction. The maximum emission intensity under 460 nm excitation was obtained at a Ba content, x, of 1.6. All Sr1.9-xBaxSiO4:Eu-0.1 samples except for Ba1.9SiO4:Eu-0.1 exhibited a temperature-driven blue-shift of the emission band. The thermostability of emission in (Sr1.9-xBax)SiO4:Eu-0.1 depended strongly on the Ba/Sr ratio. The thermal quenching temperature reached its maximum at a Ba concentration x of 1.2-1.6 and was much lower for Ba1.9SiO4:Eu-0.1(2+). (C) 2011 The Electrochemical Society. [DOI: 10.1149/1.3625282] All rights reserved.
Keywords:barium compounds;europium;light emitting diodes;phosphors;photoluminescence;quenching (thermal);spectral line shift;strontium compounds;ultraviolet spectra