화학공학소재연구정보센터
Journal of the American Chemical Society, Vol.134, No.28, 11366-11368, 2012
Electronic: Excitation Energy Transfer between Nucleobases of Natural DNA
Transfer of the electronic excitation energy in calf thymus DNA is studied by time-resolved fluorescence spectroscopy. The fluorescence anisotropy, after an initial decay starting on the femtosecond time scale, dwindles down to ca. 0.1. The in-plane depolarized fluorescence decays are described by a stretched exponential law. Our observations are consistent with one-dimensional transfer mediated by charge-transfer excited states.