Korean Journal of Rheology, Vol.10, No.1, 44-49, March, 1998
NMMO수화량이 셀룰로오스/NMMO용액의 유변학적 특성에 미치는 영향
Effect of Hydrate Level of NMMO on the Rheological Properties of Cellulose/NMMO Solutions
초록
셀룰로오스/N-methyl morpholine N-oxide(NMMO)용액에 있어서 셀룰로오스의 분자량 및 농도, 그리고 NMMO의 수화도가 유변학적 특성에 미치는 영향을 고찰하였다. 12wt.%의 경우 NMMO의 수화도가 감소할수록 더 높은 온도에서 lower Newtonian 흐름영역이 사라졌다. 15wt.%에서는 측정된 전단영역에서 lower Newtonian 유동영역이 관찰되지 않았다. 동일한 농도에서 NMMO의 수화도가 감소할수록 점도가 증가하였으나 중량평균중합도가 940인 셀룰로오스/NMMO 용액의 경우 90℃에서 점도가 오히려 낮아졌다. 뿐만 아니라 이 온도에서 power-law의 급작스런 감소도 나타났다. NMMO의 소화도가 클수록 제1법선응력차나 연신점도에 대한 온도의 영향이 증가하였다.
The rheological properties of cellulose solutions in NMMO were investigated in terms of level of hydrated water in NMMO, polymer concentration, molecular weight, and temperature. In the case of 12 wt.% cellulose solutions, the lower Newtonian flow region disappeared at higher temperature as the hydrated water level was decreased. With 15 wt.% cellulose solutions, the lower Newtonian flow region was not observed over the examined range of shear rates and temperatures. At the identical concentration, viscosity was generally increased with decreasing the hydrated water level. However, the cellulose solution of Rayonex-P with high weight-average degree of polymerization 940 showed lower viscosity at lower hydrated water level at 90℃. In addition, an abrupt decrease of power-law index was observed at this temperature. With increasing the hydrated water level the effect of temperature on first normal stress difference and elongational viscosity was more notable.
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