Synthesis of ditrimethylolpropane acrylate with low functionality for UV-curable coatings

Wei Jiang; Fan-Long Jin; Soo-Jin Park

Journal of Industrial and Engineering Chemistry, Vol.18, No.5, 1577-1581, September, 2012

DOI10.1016/j.jiec.2012.02.019 Export Citation

Synthesis of ditrimethylolpropane acrylate with low functionality for UV-curable coatings

Wei Jiang, Fan-Long Jin, and Soo-Jin Park^{1, †}

School of Chemical and Materials Engineering, Jilin Institute of Chemical Technology, Jilin City 132022, People’s Republic of China
¹Department of Chemistry, Inha University, Nam-gu, Incheon 402-751, South Korea

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An UV-curable acrylic resin, ditrimethylolpropane acrylale (DTMPA), with low functionality was synthesized by esterification of ditrimethylolpropane and acrylic acid. The influences of the synthetic process, such as catalyst, acid/alcohol ratio, inhibitor, solvent, reaction time, and temperature were discussed in detail. The chemical structure of the DTMPA was characterized by FT-IR, 1H NMR, and 13C NMR spectra. The optimal synthesis conditions of the DTMPA were determined, and the resulting product had a yield of 86.5% and pale color. The results of a UV-curing test indicate that the DTMPA has a higher curing speed than that of trimethylolpropane triacrylate.

Keywords:Acrylic resin;Esterification;Synthesis;UV-curing;Ditrimethylolpropane

[References]

Crivello JV, Polymer, 46(26), 12109 (2005)
Lu WH, Xu WJ, Wu YM, Zhou X, Lu YB, Xiong YQ, Prog. Org. Coat., 56, 252 (2006)
Kim KS, Park SJ, Carbon Lett., 11, 102 (2010)
Lee JH, Lee JS, Rhee KY, Carbon Lett., 12, 249 (2011)
Park YJ, Lim DH, Kim HJ, Park DS, Sung IK, Int. J. Adhes. Adhes., 29, 710 (2009)
Landry V, Riedl B, Blanchet P, Prog. Org. Coat., 62, 400 (2008)
Kardar P, Ebrahimi M, Bastani S, Prog. Org. Coat., 62, 321 (2008)
El-Molla MM, Dyes Pigments., 74, 371 (2007)
Shimizu H, Tsue F, Chen ZX, Kawaguchi T, Takahashi Y, J. Dent., 36, 138 (2008)
Bland MH, Peppas NA, Biomaterials., 17, 1109 (1996)
Kolarz BN, Wojaczynska M, Polymer, 39(1), 69 (1998)
Wang W, J. Eur. Polym., 39, 1117 (2003)
Matsumoto A, Tanno R, Aota H, Ikeda J, J. Eur. Polym., 37, 1071 (2001)
Wang W, J. Eur. Polym., 39, 1117 (2003)
Park SJ, Li K, Jin FL, Mater. Chem. Phys., 108(2-3), 214 (2008)
Liu H, Ye HQ, Appl. Surf. Sci., 254(15), 4432 (2008)
Li GW, Min GQ, Fei LC, Ni XY, Lu WQ, J. Colloid Interface Sci., 334(1), 8 (2009)
Wang W, Cheng K, J. Eur. Polym., 39, 1891 (2003)
Kou H, Asif A, Shi W, J. Eur. Polym., 38, 1931 (2002)
Xu D, Zhang K, Zhu X, Tetrahedron Lett., 46, 2503 (2005)
Park SJ, Jin FL, Lee JR, Macromol. Res., 13(1), 8 (2005)

[Referenced By]

[Related Articles]

[1] Crivello JV, Polymer, 46(26), 12109 (2005)

[2] Lu WH, Xu WJ, Wu YM, Zhou X, Lu YB, Xiong YQ, Prog. Org. Coat., 56, 252 (2006)

[3] Kim KS, Park SJ, Carbon Lett., 11, 102 (2010)

[4] Lee JH, Lee JS, Rhee KY, Carbon Lett., 12, 249 (2011)

[5] Park YJ, Lim DH, Kim HJ, Park DS, Sung IK, Int. J. Adhes. Adhes., 29, 710 (2009)

[6] Landry V, Riedl B, Blanchet P, Prog. Org. Coat., 62, 400 (2008)

[7] Kardar P, Ebrahimi M, Bastani S, Prog. Org. Coat., 62, 321 (2008)

[8] El-Molla MM, Dyes Pigments., 74, 371 (2007)

[9] Shimizu H, Tsue F, Chen ZX, Kawaguchi T, Takahashi Y, J. Dent., 36, 138 (2008)

[10] Bland MH, Peppas NA, Biomaterials., 17, 1109 (1996)

[11] Kolarz BN, Wojaczynska M, Polymer, 39(1), 69 (1998)

[12] Wang W, J. Eur. Polym., 39, 1117 (2003)

[13] Matsumoto A, Tanno R, Aota H, Ikeda J, J. Eur. Polym., 37, 1071 (2001)

[14] Wang W, J. Eur. Polym., 39, 1117 (2003)

[15] Park SJ, Li K, Jin FL, Mater. Chem. Phys., 108(2-3), 214 (2008)

[16] Liu H, Ye HQ, Appl. Surf. Sci., 254(15), 4432 (2008)

[17] Li GW, Min GQ, Fei LC, Ni XY, Lu WQ, J. Colloid Interface Sci., 334(1), 8 (2009)

[18] Wang W, Cheng K, J. Eur. Polym., 39, 1891 (2003)

[19] Kou H, Asif A, Shi W, J. Eur. Polym., 38, 1931 (2002)

[20] Xu D, Zhang K, Zhu X, Tetrahedron Lett., 46, 2503 (2005)

[21] Park SJ, Jin FL, Lee JR, Macromol. Res., 13(1), 8 (2005)