In order to reduce the surface recombination at the interface between the fluorine-doped tin oxide (FTO) substrate and the polysulfide electrolyte in CdS quantum-dot-sensitized solar cells (QDSCs), compact TiO2 is deposited on the FTO electrode by sputtering. The TiO2-coated CdS-sensitized solar cell exhibits enhanced power-conversion efficiency (0.52%) compared with a bare CdS-sensitized solar cell (0.23%). Charge-transfer kinetics are analyzed by impedance spectroscopy, open-circuit decay, and cyclic voltammetry. The TiO2 layer deposited on the FTO substrate acts as a blocking layer, which plays a significant role in reducing the electron back transfer from the FTO to the polysulfide electrolyte. Interestingly, with respect to the incident photon-to-current conversion efficiency (IPCE) data, asymmetric enhancement is observed from the sample with a thicker blocking layer. This is because CdS quantum dots absorb ultraviolet light completely with the TiO2 layer because of the high extinction coefficient of the CdS quantum dots compared with dye molecules. (C) 2011 Elsevier BM. All rights reserved.