In order to fabricate large scale all-solid-state Li battery, we suggested a novel structure of solid electrolyte, which is composed of porous electrolyte supported by honeycomb-type electrolyte. A possibility of fabrication of the honeycomb-supported porous electrolyte and a compatibility of this structure with all-solid-state battery were examined using LLT (Li(0.35)La(0.55)TiO(3)) solid electrolyte which is one of the anticipated solid electrolytes due to its high Li ion conductivity. A porous layer membrane with 3 dimensionally ordered (3DOM) macroporous structure was prepared by a colloidal crystal templating method. The porous honeycomb was fabricated by pushing the membrane into holes of honycomb using a needle followed by calcination. The 3DOM membrane and honeycmb electrolyte were sintered well each other. After filling the 3DOM pores with LiMn(2)O(4) cathode material, the compatibility of this novel porous honeycomb electrolyte with all-solid-state battery was examined. The LiMn(2)O(4)/porous honeycomb cell clearly demonstrated charge and discharge behaviors, indicating the porous honeycomb structure can be applied to the all-solid-state battery. The discharge capacity was 71 mA h g(-1) (1.3 mA h cm(-2)) at 30 degrees C. (C) 2011 Elsevier B.V. All rights reserved.