Journal of Polymer Science Part A: Polymer Chemistry, Vol.50, No.9, 1746-1754, 2012
Crosslinked polynorbornene particles synthesis by ring-opening metathesis polymerization in dispersion
This article proposes the first report on the synthesis of nanometric crosslinked polynorbornene particles by ring-opening metathesis polymerization in dispersion using ruthenium-based complex (PCy3)2Cl2Ru?CHPh as initiator. Stable but raspberry-shaped particles were obtained. In this study, a particular attention was paid to the influence of the crosslinker nature and addition mode on reaction kinetics and morphology of the latex particles. (C) 2012 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2012
Keywords:crosslinked particles;dispersion polymerization;poly norbornene;ring-opening metathesis polymerization (ROMP)