The present work is devoted to an attempt to understand the effect of an inorganic salt such as ferric trichloride (FeCl3) on the carbonization and degradation of carbohydrates such as beta-cyclodextrin (CD), amylose, and cellulose. Our data revealed two important observations. First, the presence of FeCl3 led to the occurrence of a low carbonization temperature of 373 K. This is a rare phenomenon, in which carbonization improvement is present even if a small amount of FeCl3 was added. Experimental results had provided evidence for the fact that a redox process was started during the low-temperature carbonization of beta-CD, causing the reduction of FeCl3 to ferrous chloride (FeCl2) by carbon materials formed in the carbonization process in air. However, the reduction process of FeCl3 produced the in situ composite nanomaterial of Fe-FeCl2 combination in nitrogen. Second, a molecule ion interaction emerged between FeCl3 and the carbohydrates in aqueous solution, resulting in a more effective degradation of the carbohydrates. Moreover, our results demonstrated that FeCl3 played the role of a catalyst during the degradation of the carbohydrates in solution. We believe that the current work not only has a significant potential application in disposal of waste carbohydrates but also could be helpful in many fields such as environmental protection, biomass energy development, and inorganic composite nanomaterials.