화학공학소재연구정보센터
Korean Journal of Chemical Engineering, Vol.29, No.11, 1585-1590, November, 2012
Evaluation of electro-coagulation method for decolorization and degradation of organic dyes in aqueous solutions
E-mail:
This research has two parts: at first part electro coagulation (EC) method was used to remove the dye Direct Black 22 (DB22 (in aqueous media. All experiments were done in a 2 liter reactor with two electrodes made of steel (SS-304) as cathodes and one aluminum electrode as anode. Parameters affecting the process, such as anode material, electrolyte concentration, current density, initial pH of solution and the initial dye concentration, were investigated. Total amount of consumed energy was used for determination of optimal conditions. According to the results obtained for DB22 at optimized conditions, color and COD removal percentage were 92% and 85%, respectively. In addition, the current efficiency for aluminum anode in removal of DB22 was 90%. At the second part of the research work, color removal by EC for six different dyes was evaluated. The results showed that dye structure and anode type are very important factors on performance of the process.
  1. Khataee AR, Zarei M, Desalination, 273(2-3), 453 (2011)
  2. Daneshvar N, Khataee AR, Ghadim ARA, Rasoulifard MH, J. Hazard. Mater., 148(3), 566 (2007)
  3. Parsa JB, Rezaei M, Soleymani AR, J. Hazard. Mater., 168(2-3), 997 (2009)
  4. Khataee AR, Kasiri MB, J. Mol. Catal. A-Chem., 328(1-2), 8 (2010)
  5. Daneshvar N, Ashassi-Sorkhabi H, Tizpar A, Sep. Purif. Technol., 31(2), 153 (2003)
  6. Merzouk B, Gourich B, Sekki A, Madani K, Chibane M, J. Hazard. Mater., 164(1), 215 (2009)
  7. Fathinia M, Khataee AR, Zarei M, Aber S, J. Mol. Catal. A-Chem., 333(1-2), 73 (2010)
  8. Can OT, Kobya M, Demirbas E, Bayramoglu M, Chemosphere., 62, 181 (2006)
  9. Bennajah M, Gourich B, Essadki AH, Vial C, Delmas H, Chem. Eng. J., 148(1), 122 (2009)
  10. Sengil IA, Ozacar M, J. Hazard. Mater., 16, 1369 (2009)
  11. Daneshvar N, Oladegaragoze A, Djafarzadeh N, J. Hazard. Mater., 129(1-3), 116 (2006)
  12. Irdemez S, Yildiz YS, Tosunoglu V, Sep. Purif. Technol., 52(2), 394 (2006)
  13. Trompette JL, Vergnes H, J. Hazard. Mater., 163(2-3), 1282 (2009)
  14. Phalakornkule C, Polgumhang S, Tongdaung W, Karakat B, Nuyut T, J. Environ. Manage., 9, 918 (2010)
  15. Kobya M, Demirbas E, Can OT, Bayramoglu M, J. Hazard. Mater., 132(2-3), 183 (2006)
  16. El-Ashtoukhy ESZ, Amin NK, J. Hazard. Mater., 179(1-3), 113 (2010)
  17. Merzouk B, Gourich B, Sekki A, Madani K, Vial C, Barkaoui M, Chem. Eng. J., 149(1-3), 207 (2009)
  18. Kim TH, Park C, Shin EB, Kim S, Desalination, 150(2), 165 (2002)
  19. Kobya M, Hiz H, Senturk E, Aydiner C, Demirbas E, Desalination, 190(1-3), 201 (2006)
  20. Khatibikamal V, Torabian A, Janpoor F, Hoshyaripour G, J. Hazard. Mater., 179(1-3), 276 (2010)
  21. Emamjomeh MM, Sivakumar M, J. Environ. Manage., 90, 1204 (2009)
  22. Kabdasli I, Arslan T, Olmez-Hanci T, Arslan-Alaton I, Tunay O, J. Hazard. Mater., 165(1-3), 838 (2009)
  23. Nanseu-Njiki CP, Tchamango SR, Ngom PC, Darchen A, Ngameni E, J. Hazard. Mater., 168(2-3), 1430 (2009)
  24. Tezcan Un U, Koparal AS, Bakir Ogutveren U, J. Environ.Manage., 90, 428 (2009)
  25. Feng JW, Sun YB, Zheng Z, Zhang JB, Li S, Tian YC, J.Environ. Sci., 19, 1409 (2007)
  26. Adhoum N, Monser L, Bellakhal N, Belgaied JE, J. Hazard. Mater., 112(3), 207 (2004)
  27. Bektas N, Akbulut H, Inan H, Dimoglo A, J. Hazard. Mater., 106(2-3), 101 (2004)
  28. Dimoglo HYAA, Cihan F, Karpuzcu M, Clean Technol.Environ. Policy., 6, 288 (2004)
  29. Mohana S, Shrivastava S, Divecha J, Madamwar D, Bioresour. Technol., 99(3), 562 (2008)
  30. Vasudevan S, Sozhan G, Ravichandran S, Jayaraj J, Lakshmi J, Sheela SM, Ind. Eng. Chem. Res., 47(6), 2018 (2008)
  31. Chen GH, Sep. Purif. Technol., 38(1), 11 (2004)
  32. Daneshvar N, Sorkhabi HA, Kasiri MB, J. Hazard. Mater., 112(1-2), 55 (2004)
  33. APHA, 14th Ed., Standard Method for the Examination of Water and Wastewater, American Public Health Association (APHA), Washington, DC (1997)