하수슬러지를 활용하여 제조한 흡착제의 고정흡착층에서의 H2S 흡착특성

박천동; 윤주영; 박영성; Chun-Dong Park; Ju-Young Youn; Yeong-Seong Park

Korean Chemical Engineering Research, Vol.50, No.4, 718-722, August, 2012

Export Citation

하수슬러지를 활용하여 제조한 흡착제의 고정흡착층에서의 H2S 흡착특성

Adsorption Characteristics of H2S on Adsorbent Made by Sewage Sludge in Fixed Bed Adsorption Column

박천동, 윤주영, 박영성^†

대전대학교 환경공학과, 300-716 대전시 동구 대학로 62

Chun-Dong Park, Ju-Young Youn, and Yeong-Seong Park^†

Department of Environmental Engineering, Daejeon University, 62 Daehak-ro, Dong-gu, Daejeon 300-716, Korea

E-mail:

초록

하수슬러지를 탄화 및 활성처리하여 흡착제를 제조하였으며, 이를 이용한 황화수소 흡착특성을 고찰하였다. 제조된 흡착제에 대한 BET 및 SEM 분석, 요오드 흡착능측정 등의 물성분석을 실시하였으며, 황화수소를 대상으로 연속식의 고정흡착층을 이용한 파과특성을 고찰하였다. 실험변수로는 흡착온도(25~45 ℃), 가스유량(0.1~2.0 liter/min), 가스농도(50~200 ppm), 형상비(L/D)(3~9) 등이 적용되었다. 실험결과, 하수슬러지는 탄화 및 활성화과정을 통해 커다란 성능향상이 이뤄짐을 알 수 있었다.

H2S adsorption characteristics of adsorbent made by sewage sludge were investigated. For analyses of the manufactured adsorbent, various methods such as Iodine adsorptivity, scanning electron microscope (SEM), and measurements of BET surface area and pore volume were adopted. As the major adsorption characteristic, breakthrough curve was measured by using a continuous fixed bed adsorption column for operating variables such as adsorption temperature (25~45 ℃), aspect ratio (L/D)(3~9), gas flow rate (0.1~2.0 liter/min) and H2S gas concentration (50~200 ppm). The experimental result showed that the carbonization and activation of sewage sludge are very important for the improvement in H2S adsorption capacity.

Keywords:Sewage Sludge;Carbonization;Activation;Iodine Adsorptivity;H2S;Breakthrough Curve

[References]

Cho BY, Jo YM, J. of Korean Society of Environmental Engineering., 30(4), 415 (2008)
Han YS, Choi WJ, Kim TJ, Kim IG, Oh KJ, J. of Korean Society of Environmental Engineering., 30(11), 1132 (2008)
Jung DH, Jeon YN, J. of KSEE., 29(5), 515 (2007)
Korean Industrial Standards, KSM 1802 (1994)
Park YT, “Activated Carbon Technology,” 1st ed., Dongwhapub, 120 (2007)
Kim HS, Chang HS, Park BB, Park YS, Min BM, J. of KSEE., 21(3), 481 (1999)
Park JH, Jun JH, Hwang KS, Lee WK, HWAHAK KONGHAK, 33(3), 301 (1995)
Jeon YH, Jung JH, Shon BH, Cho SW, Oho KJ, J. of Korean Society of Environmental Engineering., 18(8), 961 (1996)
Min BM, Yoo KP, Kim SH, HWAHAK KONGHAK, 32(2), 195 (1994)
Oh KJ, Cho KC, Jeon DY, Cho YM, J. of Korean Society for Atmospheric Environment., 21(10), 1967 (1999)
Kim HS, Park YS, Min BM, J. of Korean Society of Environmental Engineering., 23(12), 1979 (2001)
Kim HS, Park YS, J. of Korean Society for Atmospheric Environment., 15(6), 805 (1999)

[Referenced By]

[1] Cho BY, Jo YM, J. of Korean Society of Environmental Engineering., 30(4), 415 (2008)

[2] Han YS, Choi WJ, Kim TJ, Kim IG, Oh KJ, J. of Korean Society of Environmental Engineering., 30(11), 1132 (2008)

[3] Jung DH, Jeon YN, J. of KSEE., 29(5), 515 (2007)

[4] Korean Industrial Standards, KSM 1802 (1994)

[5] Park YT, “Activated Carbon Technology,” 1st ed., Dongwhapub, 120 (2007)

[6] Kim HS, Chang HS, Park BB, Park YS, Min BM, J. of KSEE., 21(3), 481 (1999)

[7] Park JH, Jun JH, Hwang KS, Lee WK, HWAHAK KONGHAK, 33(3), 301 (1995)

[8] Jeon YH, Jung JH, Shon BH, Cho SW, Oho KJ, J. of Korean Society of Environmental Engineering., 18(8), 961 (1996)

[9] Min BM, Yoo KP, Kim SH, HWAHAK KONGHAK, 32(2), 195 (1994)

[10] Oh KJ, Cho KC, Jeon DY, Cho YM, J. of Korean Society for Atmospheric Environment., 21(10), 1967 (1999)

[11] Kim HS, Park YS, Min BM, J. of Korean Society of Environmental Engineering., 23(12), 1979 (2001)

[12] Kim HS, Park YS, J. of Korean Society for Atmospheric Environment., 15(6), 805 (1999)