Kinetic study of the selective catalytic hydrogenation of 1,3-butadiene in a mixture of n-butenes

Javier A. Alves; Sergio P. Bressa; Osvaldo M. Martınez; Guillermo F. Barreto

Journal of Industrial and Engineering Chemistry, Vol.18, No.4, 1353-1365, July, 2012

DOI10.1016/j.jiec.2012.01.038 Export Citation

Kinetic study of the selective catalytic hydrogenation of 1,3-butadiene in a mixture of n-butenes

Javier A. Alves^{1, 2, †}, Sergio P. Bressa^{1, 2}, Osvaldo M. Martınez^{1, 2}, and Guillermo F. Barreto^{1, 2}

¹PROIRQ, Departamento de Ingenierıa Quımica, Facultad de Ingenierıa (UNLP), La Plata, Argentina
²Centro de Investigacion y Desarrollo en Ciencias Aplicadas ‘‘Dr. J. J. Ronco’’ (CINDECA) CCT, La Plata, CONICET, UNLP, Argentina

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The selective hydrogenation in liquid phase of 1,3-butadiene in the presence of n-butenes, over a commercial Pd/Al2O3 catalyst of the egg-shell type was studied. Experiments were carried out in a batch reactor at 44 ℃. Initial concentration were in the range of 1%-2% of 1,3-butadiene, up to 10% of 1-butene, trans-2-butene and cis-2-butene. Partial hydrogen pressures ( pH2 ) were between 1 and 8 atm. Two kinetic models were proposed to fit the experimental data. Both models give an adequate representation of the experimental data.

Keywords:Selective hydrogenation;1,3-Butadiene;1-Butene;Kinetic

[References]

Derrien ML, Selective hydrogenation applied to the refining of petrochemical raw materials produced by steam cracking, Stud. Surf. Sci. Catal. 27 (1986) 613-666 ((Chapter 18), L. Cerveny´ (Ed.), Elsevier, Amsterdam).
Bond GC, Webb G, Wells PB, Winterbottom JM, J. Catal., 1, 74 (1962)
Boitiaux JP, Cosyns J, Robert E, Appl. Catal., 35, 193 (1987)
Hub S, Touroude R, J. Catal., 114, 411 (1988)
Bressa SP, Purificacio´n Catalı´tica de 1-Buteno: Estudio Cine´ tico y Simulacio´n de un Reactor Industrial de Hidrogenacio´n Selectiva, Tesis Doctoral, Universidad Nacional de La Plata (2001)
Molnar A, Sarkany A, Varga M, J. Mol. Catal. A-Chem., 173(1-2), 185 (2001)
Kripylo P, Turek F, Hempe KD, Kirmse H, Chem. Technol., 27, 675 (1975)
Goetz J, Murzin DY, Touroude RA, Ind. Eng. Chem. Res., 35(3), 703 (1996)
Schafer P, Wuchter N, Gaube J, Stud. Surf. Sci. Catal., 130, 2051 (2000)
Boitiaux JP, Cosyns J, Derrien ML, Leger G, in: Proceedings of AIChE Spring National Meeting, Paper 1453, American Institute of Chemical Engineers (AIChE), New York (1985)
Seth D, Sarkar A, Ng FTT, Rempel GL, Chem. Eng. Sci., 62(17), 4544 (2007)
Ardiaca NO, Bressa SP, Alves JA, Martinez OM, Barreto GF, Stud. Surf. Sci.Catal., 133, 527 (2001)
Tourillon G, Cassuto A, Y. Jugnet Y, Massardier J, Bertolini JC, J. Chem. Soc. Faraday Trans., 92, 4835 (1996)
Bertolini JC, Cassuto A, Jugnet Y, Massardier J, Tardy B, Tourillon G, Surf. Sci., 349, 88 (1996)
Sautet P, Paul JF, Catal. Lett., 9, 245 (1991)
Baetzold RC, Langmuir., 3, 189 (1987)
Ardiaca NO, Bressa SP, Alves JA, Martinez OM, Barreto GF, Catal. Today, 64(3-4), 205 (2001)
Satterfield CN, AIChE J., 21, 209 (1975)
Ramachandran PA, Chaudhari RV, in: Hughes R (Ed.), 2nd ed., Three-Phase Catalytic Reactors, Topics in Chemical Engineering, Gordon and Breach Science Publishers, London (1983)
White WC, Chem. Biol. Interact., 166, 10 (2007)
Nijhuis TA, Dautzenberg FM, Moulijn JA, Chem. Eng. Sci., 58(7), 1113 (2003)
Ardiaca NO, Hidrogenacio´n Catalı´tica de Hidrocarburos Insaturados en Fase Lı´quida, Tesis Doctoral, Universidad Nacional de La Plata (2003)
Bressa SP, Martinez OM, Barreto GF, Ind. Eng. Chem. Res., 42(10), 2081 (2003)
Alves JA, Cine´ tica de la Hidrogenacio´n Catalı´tica Selectiva de 1,3-Butadieno y 1-Butino en Presencia de n-Butenos, Tesis Doctoral, Universidad Nacional de La Plata (2009)
Valcarcel A, Clotet A, Ricart JM, Delbecq JM, Sautet FP, Surf. Sci., 549, 121 (2004)
Silvestre-Albero J, Rupprechter G, Freund HJ, J. Catal., 240(1), 58 (2006)
Graboski M, Daubert T, Ind. Eng. Chem. Process Des. Dev., 18, 300 (1979)
Dahl S, Fredenslund S, Rasmussen P, Ind. Eng. Chem. Res., 30, 1936 (1991)
LarsenB, Rasmussen P, Fredenslund A, Ind. Eng. Chem. Res., 26, 2274 (1987)
Alves JA, Bressa SP, Martinez OM, Barreto GF, Chem. Eng. Res. Des., 89(4A), 384 (2011)
Reid RC, Prausnitz JM, Poling BE, Properties of Gases and Liquids, 4th ed., McGraw-Hill Book Company, New York (1987)
Akgerman A, Gainer JL, Ind. Eng. Chem. Fundam., 11(3), 373 (1972)
Gunn DJ, Int. J. Heat Mass Transfer., 21, 467 (1978)
Stewart WE, Caracotsios M, Sørensen JP, AIChE J., 38, 641 (1992)
Bressa SP, Mariani NJ, Ardiaca NO, Mazza GD, Martinez OM, Barreto GF, Comput. Chem. Eng., 25(9-10), 1185 (2001)
Bard Y, Lapidus L, Catal. Rev., 2, 67 (1968)

[Referenced By]

[1] Derrien ML, Selective hydrogenation applied to the refining of petrochemical raw materials produced by steam cracking, Stud. Surf. Sci. Catal. 27 (1986) 613-666 ((Chapter 18), L. Cerveny´ (Ed.), Elsevier, Amsterdam).

[2] Bond GC, Webb G, Wells PB, Winterbottom JM, J. Catal., 1, 74 (1962)

[3] Boitiaux JP, Cosyns J, Robert E, Appl. Catal., 35, 193 (1987)

[4] Hub S, Touroude R, J. Catal., 114, 411 (1988)

[5] Bressa SP, Purificacio´n Catalı´tica de 1-Buteno: Estudio Cine´ tico y Simulacio´n de un Reactor Industrial de Hidrogenacio´n Selectiva, Tesis Doctoral, Universidad Nacional de La Plata (2001)

[6] Molnar A, Sarkany A, Varga M, J. Mol. Catal. A-Chem., 173(1-2), 185 (2001)

[7] Kripylo P, Turek F, Hempe KD, Kirmse H, Chem. Technol., 27, 675 (1975)

[8] Goetz J, Murzin DY, Touroude RA, Ind. Eng. Chem. Res., 35(3), 703 (1996)

[9] Schafer P, Wuchter N, Gaube J, Stud. Surf. Sci. Catal., 130, 2051 (2000)

[10] Boitiaux JP, Cosyns J, Derrien ML, Leger G, in: Proceedings of AIChE Spring National Meeting, Paper 1453, American Institute of Chemical Engineers (AIChE), New York (1985)

[11] Seth D, Sarkar A, Ng FTT, Rempel GL, Chem. Eng. Sci., 62(17), 4544 (2007)

[12] Ardiaca NO, Bressa SP, Alves JA, Martinez OM, Barreto GF, Stud. Surf. Sci.Catal., 133, 527 (2001)

[13] Tourillon G, Cassuto A, Y. Jugnet Y, Massardier J, Bertolini JC, J. Chem. Soc. Faraday Trans., 92, 4835 (1996)

[14] Bertolini JC, Cassuto A, Jugnet Y, Massardier J, Tardy B, Tourillon G, Surf. Sci., 349, 88 (1996)

[15] Sautet P, Paul JF, Catal. Lett., 9, 245 (1991)

[16] Baetzold RC, Langmuir., 3, 189 (1987)

[17] Ardiaca NO, Bressa SP, Alves JA, Martinez OM, Barreto GF, Catal. Today, 64(3-4), 205 (2001)

[18] Satterfield CN, AIChE J., 21, 209 (1975)

[19] Ramachandran PA, Chaudhari RV, in: Hughes R (Ed.), 2nd ed., Three-Phase Catalytic Reactors, Topics in Chemical Engineering, Gordon and Breach Science Publishers, London (1983)

[20] White WC, Chem. Biol. Interact., 166, 10 (2007)

[21] Nijhuis TA, Dautzenberg FM, Moulijn JA, Chem. Eng. Sci., 58(7), 1113 (2003)

[22] Ardiaca NO, Hidrogenacio´n Catalı´tica de Hidrocarburos Insaturados en Fase Lı´quida, Tesis Doctoral, Universidad Nacional de La Plata (2003)

[23] Bressa SP, Martinez OM, Barreto GF, Ind. Eng. Chem. Res., 42(10), 2081 (2003)

[24] Alves JA, Cine´ tica de la Hidrogenacio´n Catalı´tica Selectiva de 1,3-Butadieno y 1-Butino en Presencia de n-Butenos, Tesis Doctoral, Universidad Nacional de La Plata (2009)

[25] Valcarcel A, Clotet A, Ricart JM, Delbecq JM, Sautet FP, Surf. Sci., 549, 121 (2004)

[26] Silvestre-Albero J, Rupprechter G, Freund HJ, J. Catal., 240(1), 58 (2006)

[27] Graboski M, Daubert T, Ind. Eng. Chem. Process Des. Dev., 18, 300 (1979)

[28] Dahl S, Fredenslund S, Rasmussen P, Ind. Eng. Chem. Res., 30, 1936 (1991)

[29] LarsenB, Rasmussen P, Fredenslund A, Ind. Eng. Chem. Res., 26, 2274 (1987)

[30] Alves JA, Bressa SP, Martinez OM, Barreto GF, Chem. Eng. Res. Des., 89(4A), 384 (2011)

[31] Reid RC, Prausnitz JM, Poling BE, Properties of Gases and Liquids, 4th ed., McGraw-Hill Book Company, New York (1987)

[32] Akgerman A, Gainer JL, Ind. Eng. Chem. Fundam., 11(3), 373 (1972)

[33] Gunn DJ, Int. J. Heat Mass Transfer., 21, 467 (1978)

[34] Stewart WE, Caracotsios M, Sørensen JP, AIChE J., 38, 641 (1992)

[35] Bressa SP, Mariani NJ, Ardiaca NO, Mazza GD, Martinez OM, Barreto GF, Comput. Chem. Eng., 25(9-10), 1185 (2001)

[36] Bard Y, Lapidus L, Catal. Rev., 2, 67 (1968)