The characterization of commercial membranes used in the separation of refined soybean oil/n-butane and n-hexane mixtures was studied in this work using different commercial ultrafiltration membranes, with cut-offs ranging from 1 to 5 kDa The membranes were used in the permeation of refined soybean oil/pressurized n-butane mixtures at 1 3 (w/w) and 1 1 (w/w) mass ratios in a continuous tangential flow module and in the permeation of soybean oil/n-hexane mixtures in a dead-end flow module. The membranes were characterized by DSC (differential scanning calorimetry), FTIR (Fourier transform spectroscopy), contact angle measurement (Goniometer), zeta potential and SEM-EDS (scanning electron microscopy with X-ray microanalysis) aiming to better understanding the phenomena involved in the permeation process Some membranes did not show any measurable permeation flux for refined soybean oil/n-butane mixtures, which may be related to their low hydrophobicity Contact angle and zeta potential measurements showed that the membrane surface hydrophilicity changes after permeation FTIR spectra showed that the membranes were fouled with oil even after washing with solvent Results obtained in this work showed that permeation caused few modifications on the surfaces of the tested membranes at the experimental conditions investigated It is shown that these polymeric membranes can be used in the separation of vegetable oils/organic solvents effectively without degradations. (C) 2010 Elsevier B V All rights reserved