In this paper, a strategy for hollow porous silica microspheres with ideally flower structure is presented. SiO(2)/PAM hybrid composite microspheres with porous were synthesized by the reaction that the porous polyacrylamide (PAM) micro-gels immersed in tetraethoxysilane (TEOS) anhydrous alcohol solution and water in a moist atmosphere, with ammonium hydroxide as a catalyst. The SiO(2) hollow microspheres with porous were obtained after calcination of the composite microspheres at 550 degrees C for 4 h. The morphology, composition, and crystalline structure of the microspheres were characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), thermo-gravimetric analysis (TGA). Fourier transform infrared spectroscopy (FI-IR), and X-ray diffraction (XRD). N(2) absorption analysis, respectively. The results indicated that the obtained hollow porous SiO(2) microspheres were a perfect flower structure. (C) 2011 Elsevier Inc. All rights reserved.