Inorganic Chemistry, Vol.39, No.13, 2706-2707, 2000
(NH4)(15)[H3Mo57V6(NO)(6)O-189(H2O)(12)(VO)(6)]center dot similar to 60H(2)O: New nanocompound obtained by chemical embellishment of {M57V6}
By chemically embellishing metal-oxygen fragments into the three outer cavities of the nanoanion [H-3-Mo57V6(NO)(6)O-183(H2O)(18)](21-) ({Mo57V6}), a new nanostructural anion formulated as [H3Mo57V6(NO)(6)O-189- (H2O)(12)(VO)(6)](15-) ({Mo57V12}) was obtained. The embellishment leads to a new nanostructural anion with some interesting results. Furthermore, the six embedded symmetry-related V2 centers have tetrahedral coordination environments and are verified as V-v ions via solid-state V-51 NMR spectrum.