[Ag-2(hfpd)(2)([14]aneS(4))(infinity), and [Ag(hfpd)([9]aneS(3))(infinity), form one-dimensional coordination polymers in which the polymeric nature of the complexes is generated by one of the thioether donors adopting unusual bridging modes to link metal centers. The strongly coordinating hfpd anions act to inhibit polymer propagation.