Experiments are carried out in a simplified drop system, which can provide a 2.3 s 10(-2) g reduced gravity period, to investigate the transition of solid material combustion behavior from normal- to reduced-gravity. A CCD camera records the diffusion flames produced by a solid fuel, Methenamine (C6H12N4), which easily sublimes and decomposes to flammable CH4 and H-2. The temperature distribution within the flame is analyzed by a monochromatic line of sight CCD measurement calibrated by a thermocouple measurement. It is revealed that during the transition period from normal- to reduced-gravity, the change of the flame shape, from tall and thin (pear like) to spherical, is faster than that of the luminance which represents the radiation intensity, indicating a relatively shorter adjustment time scale of dynamical gas flow buoyancy than that of the heat transfer when subjected to such a sudden change of gravity condition. It is also found that owing to the change of the flow affecting the oxygen and heat supply, the luminance of the flame as well as the burning rate, which was deduced based on projected area of the solid fuel according to d(2)-law, first decreases followed by an increment near the end of the drop where the gravity level slightly increases. The flame temperature gradually decreases, as the flame suddenly goes into reduced-gravity. Interpretation based on analysis of heat transfer balance and pyrolysis rate as well as the experimental results both indicate that the transitional effect is less pronounced for a smaller fuel particle than for a larger one, where buoyancy is stronger under normal-gravity whereas the flame has a larger standoff distance with increasing importance of the radiation losses from the fuel particle surface under reduced-gravity. The present work is relevant in assessing fire hazards of solid material during space travel as gravity levels change. (C) 2011 Elsevier Ltd. All rights reserved.