In this first part of a two-part study, experiments were performed to investigate condensation of FC-72 along parallel, square micro-channels with a hydraulic diameter of 1 mm and a length of 29.9 cm, which were formed in the top surface of a solid copper plate. The condensation was achieved by rejecting heat to a counter flow of water through channels brazed to the underside of the copper plate. The FC-72 entered the micro-channels slightly superheated, and operating conditions included FC-72 mass velocities of 68-367 kg/m(2) S. FC-72 saturation temperatures of 57.2-62.3 degrees C, and water mass flow rates of 3-6 g/s. Using high-speed video imaging and photomicrographic techniques, five distinct flow regimes were identified: smooth-annular, wavy-annular, transition, slug, and bubbly, with the smooth-annular and wavy-annular regimes being most prevalent. A detailed pressure model is presented which includes all components of pressure drop across the micro-channel. Different sub-models for the frictional and accelerational pressure gradients are examined using the homogenous equilibrium model (with different two-phase friction factor relations) as well as previous macro-channel and mini/micro-channel separated flow correlations. Unexpectedly, the homogenous flow model provided far more accurate predictions of pressure drop than the separated flow models. Among the separated flow models, better predictions were achieved with those for adiabatic and mini/micro-channels than those for flow boiling and macrochannels. (C) 2011 Elsevier Ltd. All rights reserved.