A curved square channel in laminar flow is numerically investigated based on the classical Navier-Stokes equations from the viewpoint of the field synergy principle. The field synergy principle may accurately describe the curved channel has higher convective heat transfer rate in the case that the heat transfer surface is specified on the outer wall, rather than on the inner wall. The field synergy principle could also be responsible for that the curved channel can enhance the convective heat transfer significantly at the cost of the slight increase of the flow resistance. The field synergy number represents the degree of the synergy between the temperature gradient and the velocity vector, the higher field synergy number leads to the higher convective heat transfer rate under the same Reynolds number and Prandtl number. The field synergy number plays the same positive role in the convective heat transfer whether the fluid is heated or cooled. (C) 2011 Elsevier Ltd. All rights reserved.