Inorganic Chemistry, Vol.38, No.25, 5913-5915, 1999
C-S bond cleavage in CpRu(PPh3)(2)SCH2CH=CH2 to give the trimer (CpRu)3(mu(3)-S)(2)(mu-SCH2CH=CH2)
C-S Bond Cleavage in CpRu(PPh3)(2)SCH2CH=CH2 To Give the Trimer (CPRu)(3)(mu(3)-S)(2)(mu-SCH2CH=CH2) CpRu(PPh3)(2)SCH2CH=CH2 (1) loses two PPh3 ligands in refluxing toluene and undergoes C-S bond cleavage to give the sulfide-bridged trimer (CpRu)(3)(mu(3)-S)(2)(mu SCH2CH=CH2) (6).
Keywords:ALLYL ENOL CARBONATES;R = 1-C3H7;OXIDATIVE ADDITION;TRAPPINGREACTIONS;DATIVE LIGANDS;SULFIDES;HYDRODESULFURIZATION;MECHANISM;COMPLEXES;CP-STAR-2ZR=S