Inorganic Chemistry, Vol.50, No.15, 6850-6852, 2011
A 3D Cu-II Coordination Framework with mu(4)-/mu(2)-Oxalato Anions and a Bent Dipyridyl Coligand: Unique Zeolite-Type NiP2 Topological Network and Magnetic Properties
The reaction of copper(II) nitrate, oxamide, and an angular bridging ligand 2,5-bis(4-pyridyl)-1,3,4-oxadiazole (4-bpo) under hydrothermal conditions affords a 3D pillared-layer coordination framework {[Cu-2(4-bpo)(ox)(2)](H2O)(4)}(n) (1) (ox = oxalate), featuring the unique zeolite-type NiP2 network and interesting properties.